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Ankerite

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Ankerite
General
CategoryCarbonate mineral
Formula
(repeating unit)
Ca(Fe,Mg,Mn)(CO3)2
IMA symbolAnk[1]
Strunz classification5.AB.10
Crystal systemTrigonal
Crystal classRhombohedral (3)
H–M symbol: (3)
Space groupR3
Unit cella = 4.8312(2)
c = 16.1663(3) [Å]; Z = 3
Identification
ColorBrown, yellow, white
Crystal habitChrystals rhombohedral with curved faces; columnar, stalactitic, granular, massive
TwinningSimple t {0001}, {1010}. {1120}
CleavagePerfect on {1011}
FractureSubconchoidal
TenacityBrittle
Mohs scale hardness3.5–4.0
LusterVitreous to pearly
StreakWhite
DiaphaneityTranslucent to transparent
Specific gravity2.93–3.10
Optical propertiesUniaxial (−)
Refractive indexnω = 1.690–1.750
nε = 1.510–1.548
Birefringenceδ = 0.180–0.202
DispersionStrong
References[2][3][4]

Ankerite, also known as brown spar[5]: 258  (German: braunspat) is a calcium, iron, magnesium, manganese carbonate mineral of the group of rhombohedral carbonates with the chemical formula Ca(Fe,Mg,Mn)(CO3)2. In composition it is closely related to dolomite, but differs from this in having magnesium replaced by varying amounts of iron(II) and manganese. It forms a series with dolomite and kutnohorite.[3]

Name and history

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It was first recognized as a distinct species by Wilhelm von Haidinger in 1825, and named for Matthias Joseph Anker (1771–1843) of Styria, an Austrian mineralogist.[3]

In 19th-century mineralogy, as well as in mining and among geologists, ankerite and its close analogues from the dolomite series were more often known by the capacious, expansive name of ″brown spar″.[6]: 34  This is partly due to the fact that this mineral is the extreme (with the highest content of divalent iron ions) member of the dolomite-ankerite isomorphic series, as a result of which dirty-brown varieties of dolomite, contaminated with impurities, could also be encountered under the name of brown spar.[7]: 70 

Properties

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The crystallographic and physical characters resemble those of dolomite and siderite. The angle between the perfect rhombohedral cleavages is 73° 48′, the hardness is 3.5 to 4, and the specific gravity is 2.9 to 3.1. The color is white, grey or reddish to yellowish brown.[8]

Genesis

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Ankerite occurs with siderite in metamorphosed ironstones and sedimentary banded iron formations. It also occurs in carbonatites. In sediments it occurs as authigenic, diagenetic minerals and as a product of hydrothermal deposition.[2] It is one of the minerals of the dolomite-siderite series, to which the terms brown-spar, pearl-spar and bitter-spar have been historically loosely applied.[8]

It has been found in Western Tasmania, in mines in Dundas, Tasmania.

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See also

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References

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  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b Handbook of Mineralogy
  3. ^ a b c Ankerite on Mindat.org
  4. ^ Ankerite on Webmineral
  5. ^ 礦物學名詞: (俄英中对照試用本) Mineralogical Terminology (Russian-English-Chinese version). — Beijing: 中國科学院. 編譯出版委員会 Compilation and Publication Committee of Chinese Academy of Sciences, 1956. — 279 p.
  6. ^ Bulletin of the United States National Museum. No.30. Publiched under the Directions of the Smitsonian Institution. — Washington: Government Printing Office, 1885.
  7. ^ Krivovichev V. G. Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0
  8. ^ a b  One or more of the preceding sentences incorporates text from a publication now in the public domainSpencer, Leonard James (1911). "Ankerite". In Chisholm, Hugh (ed.). Encyclopædia Britannica. Vol. 2 (11th ed.). Cambridge University Press. p. 58.
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